Turns out Gardevoir learned sweet scent behaves as an aphrodisiac to human women, allowing her to grow a small harem [Officer Jenny/Nurse Joy/Jessie/Ash's Mom] (didn't catch name of artist, source in comments)
Something about the ritual of putting on the uniform and her hair made it very easy to relax. Ponytail up, mind out. [Art by Haruhisky, Manip by Sleepyhead97]